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A new 3D Ag(I) coordination polymer {[Ag(AZDB)_(0.5)(bpe)_(0.5)]·H_2O}_n(1) has been papared by azobenzene-3,3?-dicarboxylicate(H_2AZDB), 1,2-bis(4-pyridyl)ethylene(bpe) and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyses, infrared spectrum(IR), powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA). The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag_2O_2 ribbon and pyridyl/carboxylicate mixed system, which features a 2-nodal(4, 6)-connected fsc net with a(44·610·8)(44·62) topology.Moreover, the photoluminescent properties have also been discussed.
A new 3D Ag (I) coordination polymer {[Ag (AZDB) _ (0.5) (bpe) _ (0.5)] · H_2O} _n (1) has been papared by azobenzene- 1,2-bis (4-pyridyl) ethylene (bpe) and silver salts via hydrothermal method. The compound was fully characterized by single-crystal X-ray diffraction, elemental analyzes, infrared spectrum (IR), powder X-ray diffraction PXRD) and thermogravimetric analysis (TGA). The strucrural analysis indicate that compound 1 shows a 3D pillared-layer framework constructed from a unique 1D Ag_2O_2 ribbon and pyridyl / carboxylicate mixed system, which features a 2-nodal (4,6) -connected fsc net with a (44 · 610 · 8) (44 · 62) topology.Moreover, the photoluminescent properties have also been discussed.