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4,6-二甲基-5-苄基-2-嘧啶硫醇(dmbzpymtH)与CuI和NaOH反应得到化合物[Cu(dmbzpymt)]6.2CHCl3(1.2CHCl3),该化合物通过元素分析、红外光谱等表征.X射线衍射法测得该晶体属于三斜晶系,空间群为P墿,晶胞参数:a=1.531 4(3)nm,b=1.542 9(3)nm,c=1.970 6(4)nm,α=108.401(4)°,β=91.540(3)°,γ=104.076(4)°,V=4.258 0(14)nm3,C80H72Cl6Cu6N12S6,Mr=1 987.80,Dc=1.550 g/cm3,Z=2,F(000)=2 016,R1=0.103 9,wR2=0.192 5,S=1.069.六个铜原子通过六个dmbzpymt桥联,形成一个Cu6S6结构.Cu-N,Cu-S平均键长分别为0.203 5 nm,0.224 8 nm.
Reaction of 4,6-dimethyl-5-benzyl-2-pyrimidinethiol (dmbzpymtH) with CuI and NaOH gave compound [Cu (dmbzpymt)] 6.2CHCl3 (1.2CHCl3) which was characterized by elemental analysis, The crystal belongs to the triclinic system with P 墿 space group and the unit cell parameters are as follows: a = 1.531 4 (3) nm, b = 1.542 9 (3) nm, c = 1.970 6 ), α = 108.401 (4) °, β = 91.540 (3) °, γ = 104.076 (4) °, V = 4.258 0 (14) nm3, C80H72Cl6Cu6N12S6, Mr = 1 987.80, Dc = 1.550 g / cm3, Z = 2, F (000) = 2 016, R1 = 0.103 9, wR2 = 0.192 5, S = 1.069.The six copper atoms were bridged by six dmbzpymt to form a Cu6S6 structure.The Cu-N, Cu- The bond lengths are 0.203 5 nm and 0.224 8 nm, respectively.