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合成了配合物[Mn(N3)2(Phen)2],并通过X-射线单晶衍射确定了其晶体结构。晶体结构属于三斜晶系,空间群为P1,晶胞参数为:a=0.963 06(19)nm,b=1.342 5(3)nm,c=1.692 9(3)nm;α=87.00(3)°,β=89.00(3)°,γ=86.00(3)°,Z=1。配合物[Mn(N3)2(Phen)2]的每个分子中,锰(II)离子采取六配位的变形八面体几何构型,每个锰原子分别与2个邻菲咯啉的氮原子及2个叠氮基团的氮原子形成配位键。热重分析显示标题化合物有较高的热稳定性。
The complex [Mn (N3) 2 (Phen) 2] was synthesized and its crystal structure was confirmed by X-ray single crystal diffraction. The crystal structure belongs to the triclinic system with the space group P1 and the unit cell parameters are: a = 0.963 06 (19) nm, b = 1.342 5 (3) nm, c = 1.692 9 ) °, β = 89.00 (3) °, γ = 86.00 (3) °, Z = 1. In each molecule of complex [Mn (N3) 2 (Phen) 2], the manganese (II) ions adopt hexacoordinated deformed octahedron geometry, and each manganese atom is respectively coordinated with two phenanthroline nitrogen The atom and the two nitrogen atoms of the azide group form a coordinate bond. Thermogravimetric analysis shows that the title compound has higher thermal stability.