【摘 要】
：
The title complex 1, {[CuEu(Hbidc)(HO)]·HO} (Hbidc = 1H-benzimidazole- 5,6-dicarboxylic acid), has been solvothermally synthesized and structurally characteriz
【机 构】
：
Key Laboratory for Organic Electronics & Information Displays (KLOEID) and Institute of Advanced Mat
论文部分内容阅读
The title complex 1, {[CuEu(Hbidc)(HO)]·HO} (Hbidc = 1H-benzimidazole- 5,6-dicarboxylic acid), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Complex 1 crystallizes in triclinic, space group P, CHCuEuNO, M = 713.86, D = 2.208 g/cm, F(000) = 700, GOOF = 0.950, Z = 2, the final R = 0.0531 and wR = 0.1068 for I > 2σ(I).Complex 1 possess a tape-like chain structure consisting of EuCO and CuEuCNO metallic rings alternatively arranged and is the first 3d-4f heterometallic complex based on the 1H-benzimidazole-5,6-dicarboxylato ligand (Hbidc).Plenty of hydrogen-bonding and π…π stacking interactions connect the 1D chains to construct a 3D supramolecular architecture.
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