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A new compound, (C 6H 6N 3) 7(PMo Ⅵ 12 O 40 )(PMo ⅤMo Ⅵ 11 O 40 )·2CH 3CH 2OH·5H 2O, was synthesized and characterized by means of elemental analyses, IR spectroscopy, 1H NMR spectroscopy and single crystal {X ray} diffraction. This is the first example of benzotriazole polyoxometalates species. The compound crystallized in a triclinic space group P 1 with a =1 8378(4) nm, b =1 9078(4) nm, c =2 1037 (4) nm, α ={63 41(3)°}, β =64 31(3)°, γ =68 38(3)°, V =5 803(2) nm 3, Z =2, R 1=0 0486, wR 2=0 1357. The X ray crystallographic study showed that the crystal structure was constructed by electrostatic interactions and hydrogen bonds between dodecamolybdophosphorate anions and protonated benzotriazole cations. The electrochemical behavior and the reduction of nitrite and hydrogen peroxide electrocatalyzed by the title compound were studied.
A new compound, (C 6H 6N 3) 7 (PMo Ⅵ 12 O 40) (PMo ⅤMo VI 11 O 40) · 2CH 3CH 2OH · 5H 2 O, was synthesized and characterized by means of elemental analyzes, IR spectroscopy, 1H NMR spectroscopy This compound is crystallized in a triclinic space group P 1 with a = 1 8378 (4) nm, b = 1 9078 (4) and single crystal {X ray} diffraction. This is the first example of benzotriazole polyoxometalates species. α = 63 41 (3) ° }, β = 64 31 (3) °, γ = 68 38 (3) °, V = 5 803 (2) ) X 3, Z = 2, R 1 = 0 0486, wR 2 = 0 1357. The X ray crystallographic study showed that the crystal structure was constructed by electrostatic interactions and hydrogen bonds between dodecamybdophosphorate anions and protonated benzotriazole cations. The electrochemical behavior and the reduction of nitrite and hydrogen peroxide electrocatalyzed by the title compound were studied.