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The crystal structure of the title compound, [enH2][Fe{MoV6O12(OH)3(HPO4)-(H2PO4)3}2].6en.6H2O (en = H2NCH2CH2NH2), hydrothermally synthesized from a mixture of Na2MoO4@2H2O, Fe2(SO4)3, H3PO4, H2N(CH2)2NH2 and water, has been determined by singlecrystal X