Sulphur-doped ordered mesoporous carbon with enhanced electrocatalytic activity for the oxygen reduc

来源 :Journal of Energy Chemistry | 被引量 : 0次 | 上传用户:liu8423824
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Metal-free,heteroatom functionalized carbon-based catalysts have made remarkable progress in recent years in a wide range of applications related to energy storage and energy generation.In this study,high surface area mesoporous ordered sulphur doped carbon materials are obtained via one-pot hydrothermal synthesis of carbon/SBA-15 composite after removal of in-situ synthesized hard template Si O_2.2-thiophenecarboxy acid as sulphur source gives rise to sulphur doping level of 5.5 wt%.Comparing with pristine carbon,the sulphur doped mesoporous ordered carbon demonstrates improved electro-catalytic activity in the oxygen reduction reaction in alkaline solution. Metal-free, heteroatom functionalized carbon-based catalysts have made remarkable progress in recent years in a wide range of applications related to energy storage and energy generation. In this study, high surface area mesoporous ordered sulfur doped carbon materials are obtained via one-pot hydrothermal synthesis of carbon / SBA-15 composite after removal of in-situ synthesized hard template Si02_2-thiophenecarboxylate as sulfur source gives rise to sulfur doping level of 5.5 wt%. Comparing with pristine carbon, the sulfur doped mesoporous ordered carbon demonstrates improved electro-catalytic activity in the oxygen reduction reaction in alkaline solution.
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