用溶液法由液体端羧基聚丁二烯（ＣＴＰＢ）及液体端羧基聚（丁二烯－ｃｏ－丙烯腈）（ＣＴＢＮ）合成了Ｌｉ＋、Ｎａ＋、Ｋ＋、Ｍｇ２＋、Ｚｎ２＋、Ａｌ３＋的遥爪型离聚体．考察了反应条件对离聚体形成的影响及离聚体稀溶液的性质。并用红外光谱，透射电子显微镜、动态粘弹谱仪研究和表征了部分ＣＴＰＢ、ＣＴＢＮ遥爪型离聚体． The teleconnection of Li +, Na +, K +, Mg2 +, Zn2 + and Al3 + was synthesized by solution method from liquid carboxyl terminated polybutadiene (CTPB) and liquid carboxyl terminated poly (butadiene-co- acrylonitrile) Polymer. The effects of reaction conditions on the formation of ionomers and the properties of dilute solutions of ionomers were investigated. Some CTPB and CTBN telechelic ionomers were studied and characterized by FTIR, TEM and dynamic viscoelastic spectroscopy.