以二茂铁乙酸钠为配体,4,4′-bpy为辅助桥联配体,合成了一个新的一维链状配位聚合物[Pb(η2-OOCCH2Fc)2(4,4-′bpy)]n(Fc=二茂铁),并用X-射线单晶结构分析法测定了其晶体结构。对标题配合物以及二茂铁乙酸钠配体的荧光性质研究结果表明:该配合物的荧光性能主要取决于配体的性质。 A new one-dimensional chain coordination polymer [Pb (η2-OOCCH2Fc) 2 (4,4- ’) was synthesized by using ferric acetate as ligand and 4,4’-bpy as an auxiliary bridging ligand. bpy)] n (Fc = ferrocene) was synthesized and its crystal structure was determined by X-ray single crystal structure analysis. Fluorescent properties of title complexes and sodium ferrocene ligands show that the fluorescence properties of the complexes mainly depend on the nature of the ligands.