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Under hydrothermal condition, the reaction of 2-naphthoxyacetic acid with ZnCl2 and 4,4’-bipyridine (4,4’-bipy) has afforded a new Zn(II) compound, [Zn(C12H9O3)2(C10H8N2)]n·nH2O 1, which was structurally characterized by single-crystal X-ray diffract