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α-{3-[2-hydroxy-3-(N-methyl-N-hydroxyethylamino)propoxy]propyl}-ω-butylpolydimethylsiloxanes Ⅲ with various moleculax weights were prepared by epoxy addition of α-[3-(2,3-epoxy-propoxy)propyl]-ω-butylpolydimethylsiloxanes Ⅱ and Nmethylmonoethanolamine.At each step.the outcome compounds were characterized through FT-IR and NMR spectra,the results showed that each step was successfully carried out and objective products were achieved.