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近几年,在探索具有高电导或金属性电导的固体材料时,已对过渡金属的有机金属络合物发生了兴趣。例如Pt(bipy)_2·TCNQ复合物,以及最近报道的具有压片室温电导率在0.04~1.9(Ω,cm)~(-1)的CuL_2·TCNQ_2(L=bipy,phen)。我们在合成了一系列具有不同化学比的过
In recent years, there has been an interest in organometallic complexes of transition metals when exploring solid materials with high conductance or metallic conductance. Such as Pt (bipy) 2 · TCNQ complex, and the recently reported CuL_2 · TCNQ_2 (L = bipy, phen) with a sheet room temperature conductivity of 0.04-1.9 (Ω, cm) -1. We are synthesizing a series of different chemical ratios