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利用循环伏安法测定了四核钼簇合物Ｍｏ_４Ｓ_４（μ－ＯＡｃ）_２（ｄｔｐ）_４在ＣＨ_３ＣＮ，ＤＭＦ，ＤＭＳＯ等溶剂中的氧化还原半波电位（Ｅ_（１／２）），对其氧化还原峰进行了归属，结果表明在ＣＨ_３ＣＮ中存在一个单电子的氧化过程和二个单电子的还原过程，而在ＤＭＦ和ＤＭＳＯ中只存在二个单电子的还原过程。同时还探讨了溶剂的ＤＮ数对该簇合物电化学性质的影响。
The redox potential (E_ (1/2)) of Mo_4S_4 (μ-OAc) _2 (dtp) _4 in CH_3CN, DMF and DMSO was measured by cyclic voltammetry Redox peaks were assigned. The results showed that there was one single electron oxidation and two single electron reduction processes in CH_3CN, but only two single electron reduction processes in DMF and DMSO. The effects of solvent DN number on the electrochemical properties of the cluster were also discussed.