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1983年Ｔａｒａｍａｓｓｏ等[1]报导了钛硅沸石ＴＳ-1的合成。由于在用稀Ｈ2Ｏ2为氧化剂的低温氧化反应中ＴＳ-1的突出催化性能,所以近年来钛硅沸石的合成、表征及催化应用研究一直是热点课题。经典的钛硅沸石合成需要采用昂贵的模板剂-不含碱金属离子的四丙基氢氧化铵(Ｔ...
1983 Taramasso et al [1] reported the synthesis of titanium silicalite TS-1. Due to the prominent catalytic performance of TS-1 in the low-temperature oxidation reaction using diluted H2O2 as oxidant, the synthesis, characterization and catalytic application of titanium silicalite have been hot topics in recent years. Classic titanium silicalite synthesis requires the use of expensive templating agents - Alkali metal ions without tetrapropylammonium hydroxide (T ...