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A novel anionic organotin(IV) complex {[(p-ClC6H4CH2)Sn(H2O)(Cl)2OCO-CH(O)CH(O)CO2Sn(H2O)(Cl)2(p-ClC6H4CH2)]?2(HNEt3)}(1) was synthesized by the reaction of di(p-chlorobenzy)tin dichloride with the D-tartaric acid in 2:1 molar in the presence of an organi