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The crystal structure of 4-phenyl-5-(l -t-butyl-5 -methyl-4 -pyrazolyl)- 1,2,4-triazol-3-thione 5 (CI6HI9N5S, Mr = 313.42) has been determined by single-crystal X-ray diffractionanalysis. The crystal belongs to monoclinic, space group P21/c with a = 6.680