合成了环糊精二聚体(trans-Azoβ-CD Dimer)及侧链含金刚烷(Ad)的聚丙烯酰胺(PAM-Ad),利用trans-Azoβ-CD Dimer与PAM-Ad侧链的Ad基团的主客体识别作用构筑了一类超分子体系。2D NMR测定结果表明,trans-Azoβ-CD Dimer和PAM-Ad的主客体相互作用是通过β-CD空腔和疏水体Ad形成包结络合物进行的。环糊精二聚体trans-Azoβ-CD Dimer和聚合物PAM-Ad两者之间的缔合程度受trans-Azoβ-CD Dimer和PAM-Ad的浓度、温度、盐浓度以及trans-Azoβ-CD Dimer光异构的影响。 The trans-Azoβ-CD Dimer and the polyacrylamide (PAM-Ad) with adamantane side chains were synthesized. The trans-Azoβ-CD Dimer and Ad- Host-guest group recognition role to build a class of supramolecular system. The results of 2D NMR showed that the host-guest interaction between trans-Azoβ-CD Dimer and PAM-Ad was through the inclusion complex of β-CD cavity and hydrophobic Ad. The degree of association between the cyclodextrin dimer trans-Azoβ-CD Dimer and the polymer PAM-Ad is determined by the concentration, temperature, salt concentration of trans-Azoβ-CD Dimer and PAM-Ad as well as trans-Azoβ-CD Dimer photo-isomerization effects.