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  5. Oxidation of Alcohols Catalyzed by Ruthenium Complexes with Iodosylbenzene as Oxidant

Oxidation of Alcohols Catalyzed by Ruthenium Complexes with Iodosylbenzene as Oxidant

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：cczxokli
【摘 要】
：
Five ruthenium complexes such as Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin,Quin-Ru-Quin and Bipy-Ru-Quin (where Phen=1, 10-phenanthroline, Quin=8-hydroxyquinolin
【作 者】
：
Zi Qiang LEI Qiao Xiang KANG X 
【机 构】
：
Key Laboratory of Polymer Materials of Gansu Province
【出 处】
：
中国化学快报（英文版）
【发表日期】
：
2004年期
【关键词】
：
Alcohols catalytic oxidation ruthenium complexes iodosylbenzene 
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论文部分内容阅读
Five ruthenium complexes such as Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin,Quin-Ru-Quin and Bipy-Ru-Quin (where Phen=1, 10-phenanthroline, Quin=8-hydroxyquinoline,Bipy=2, 2′-bipyridine) were synthesized and used as catalysts for the oxidation of benzylic and primary aliphatic alcohols with iodosylbenzene as oxidant. The oxidations were carried out at room temperature, affording the corresponding aldehydes and ketones with high selectivity.
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