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The title compound,α,α,β,β-5,10,15,20-tetrakis(2-aminophenyl)porphyrin,has been obtained and characterized by single-crystal X-ray diffraction.The crystal belongs to the monoclinic system,space group C2/c with a = 31.804(6),b = 19.314(4),c = 12.872(3),β = 90.592(3)°,Z = 4,V = 7907(3) 3,Dc = 1.193 g/cm3,Mr = 1419.67,λ(MoKα) = 0.71073 ,μ = 0.073 mm-1,F(000) = 2984,R = 0.0773 and wR = 0.2045.The crystallographic analysis indicates the existence of N-H···π intermolecular interactions and hydrogen bonds which link the complex molecules into a 3D network structure.
The title compound, α, α, β, β-5,10,15,20-tetrakis (2-aminophenyl) porphyrin, has been obtained and characterized by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group C2 / c with a = 31.804 (6) b = 19.314 (4) c = 12.872 (3) β β = 90.592 (3) ° Z = 4 V = 7907 3 Dc = 1.193 g / cm3, Mr = 1419.67, λ (MoKα) = 0.71073 , μ = 0.073 mm -1, F (000) = 2984, R = 0.0773 and wR = 0.2045.The crystallographic analysis indicates the existence of NH ·· Π intermolecular interactions and hydrogen bonds which link the complex molecules into a 3D network structure.