由于高分子醛化反应催化剂具有工业应用的潜在的可能性,因而它的研究受到了广泛的重视.而高分子催化剂的稳定性是一重要的性能指标.含膦高分子金属铑络合物对于烯烃的醛化是一类活性和选择性很高的催化剂.但是,膦配体在醛化条件下易被氧化而导致金属的流失,这就使人们去探求非膦配体-铑络合物用于催化烯烃醛化的可 Due to the potential of industrial application of polymer hydroformylation catalyst, its research has received extensive attention, and the stability of polymer catalyst is an important performance index.Phosphorus-containing high molecular weight rhodium complexes for Alkylation of olefins is a class of highly active and selective catalysts. However, phosphine ligands are readily oxidized under hydroformylation conditions resulting in the loss of metals, leading to the search for non-phosphine ligands, rhodium complexes May be used to catalyze the hydroformylation of olefins