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采用多靶轮流溅射技术,用Ti和六方氮化硼(h-BN)反应合成了Ti-B-N薄膜,采用XRD、TEM和显微硬度计研究了薄膜的微结构及其力学性能。结果表明,室温下沉积的Ti-B-N薄膜为非晶体的Ti(N,B)化合物,其硬度达到HK2470;高温下沉积的薄膜为TiN结构类型的Ti(N,B)晶体,薄膜在晶化后硬度略有降低。
The Ti-B-N thin films were synthesized by the multi-target rotation sputtering technique with Ti and hexagonal boron nitride (h-BN). The microstructure and mechanical properties of the films were investigated by XRD, TEM and microhardness tester. The results show that the Ti-B-N thin film deposited at room temperature is an amorphous Ti (N, B) compound with a hardness of HK2470. The TiN thin film deposited at high temperature is Ti (N, B) After the crystallization hardness slightly lower.