We report the design,synthesis,structure,and properties of two complex layered phosphide nitrides,AkTh2Mn4P4N2 (Ak =Rb,Cs),which contain anti-fluorite-type[Mn2P2]bilayers separated by fluorite-type[Th2N2]layers as a result of the intergrowth between AkMn2
Block copolymers not only combine properties of different segments but also generate new application prospects.Poly(α-amino ac-id)-b-poly(tetrahydrofuran)-b-poly(α-amino acid) (PAA-PTHF-PAA) is one of the copolymers.In this contribution,di-hydroxyl-ended
Nanoporous (NP) Ge/Ag composite is controllably fabricated via one simple dealloying method under mild conditions.After corroding the well-designed Ge9Ag1Al90 source alloy,the resulting Ge/Ag consists of the three dimensional (3D) interconnected Ge networ
Herein,we report a rational construction of Au@Ag/C@SiO2 system with Au@Ag core-shell nanoparticles (NPs) as a promising pho-tocatalyst based on the plasmonic coupling effect for the first time towards the photoreduction of nitroaromatic compounds under v
Detection of hydrazine originated from electrochemical media has recently gained considerable attention in the sensing field.Herein,to improve electron transfer capacity,a polyoxometalate metal-organic framework (POMOF,NENU-3) is in-situ nucleated onto th
Important progress has been made in the development of energetic molecules with high performance by computer-aided molecular design in recent years,but structural novelty of organic scaffolds is insufficient.In this work,we propose an intra-ring bridging
Nineteen unprecedented 7-methoxylated caged xanthones (1-19) were-isolated from the twigs of Garcinia oligantha under the guidance of NMR spectroscopy.Their structures and absolute configurations were demonstrated by extensive spectroscopic data,single-cr
Chemical analysis of single cells plays essential roles in both fundamental research and clinical applications.In this work,the electrochemiluminescence (ECL) generated at vertically aligned gold microtube electrode ensembles (MEEs) was applied for the lo
Sn-based composites are considered as one of the promising anode materials for sodium-ion batteries (SIBs) due to their high theoretical capacities and suitable operation voltages.However,they suffer the huge volume change and unstable electrolyte/electro
In the past a few years,there has been significant progress in theoretical characterizations of gas-surface reaction dynamics at the atomic level.One of the major breakthroughs is the machine learning representations of the potential energy surfaces and r