【摘 要】
:
The main difficulty in the extensive commercial use of polymer electrolyte membrane fuel cells (PEMFCs) is the use of noble metals such as Pt-based electrocatalyst at the cathode,which is essential to ease the oxygen reduction reaction (ORR) in fuel cells
【机 构】
:
College of Materials Science and Engineering, Sichuan University, Chengdu 610065, Sichuan, China;Wes
论文部分内容阅读
The main difficulty in the extensive commercial use of polymer electrolyte membrane fuel cells (PEMFCs) is the use of noble metals such as Pt-based electrocatalyst at the cathode,which is essential to ease the oxygen reduction reaction (ORR) in fuel cells (FCs).To eliminate the high loading of Pt-based electrocatalysts to minimize the cost,extensive study has been carried out over the previous decades on the non-noble metal catalysts.Development in enhancing the ORR performance of FCs is mainly due to the doped carbon materials,Fe and Co-based electrocatalysts,these materials could be considered as probable substitutes for Pt-based catalysts.But the stability of these non-noble metal electrocatalysts is low and the durability of these metals remains unclear.The three basic reasons of instability are:(i) oxidative occurrence by H2O2,(ii) leakage of the metal site and (iii) protonation by probable anion adsorption of the active site.Whereas leakage of the metal site has been almost solved,more work is required to understand and avoid losses from oxidative attack and protonation.The ORR performance such as stability tests are usually run at low current densities and the lifetime is much shorter than desired need.Therefore,improvement in the ORR activity and stability are the key issues of the non-noble metal electrocatalyst.Based on the consequences obtained in this area,numerous future research directions are projected and discussed in this paper.Hence,this review is focused on improvement of stability and dnrability of the non-noble metal electrocatalyst.
其他文献
The graphene coating was deposited on the surface of Ni foam using the chemical vapor deposition process.A large amount of flower-like ZnCo2O4 microspheres with short nanowires were formed on bare Ni foam by hydrothermal method,while large-scale ZnCo2O4 n
Nanostructured and nanosized materials are widely applied to tackle the pressing challenges associated with energy conversion.In this conceptual review,rather than highlighting separate examples,we aim to give a general overview about where and how nanost
Highly efficient and non-precious catalysts are imperative for oxygen reduction reaction (ORR) to replace Pt/C.Anchoring efficient active species to carbon supports is a promising and scalable strategy.Here we synthesize Cu nanoparticles and noncrystallin
The electrochemical oxidation of formic acid has been attracting significant attention in the past few years due to the great potential prospect of direct formic acid fuel cell (DFAFC) in applications,including high theoretical open circuit potential (1.4
Conjugated polymers are commonly used as effective hole transport materials (HTMs) for preparation of high-performance perovskite solar cells.However,the hydrophobic nature of these materials renders it difficult to deposit photovoltaic perovskite layers
The reduction of CO2 emission is crucial for the mitigation of climate change.A considerable amount of industrial CO2 can be absorbed in the form of carbonates through high-temperature sorption processes.In this regard,the efficient conversion of carbonat
A facile synthesis of vanadium oxide with reduced graphene oxide (rGO) is developed and used as cathode material for lithium ion batteries.VO2(B) nanorods and VO2(B)-rGO composite were prepared by a hydrothermal method using NaVO3 precursor and sodium oxa
Quinary oxynitride BaNb0.5Ta0.5O2N crystals were fabricated through the partial nitridation and acidification of the KCl flux grown Ba5Nb2Ta2O15 crystals.The parameters of both the solute concentrations and cooling rates are optimized for the KCl flux gro
Reverse water gas shift (RWGS) reaction can be served as a pivotal stage of transitioning the abundant CO2 resource into chemicals or hydrocarbon fuels,which is attractive for the CO2 utilization and of eventually significance in enabling a rebuilt ecolog
We have synthesized two photovoltaic molecules (HEX-3TVT-ID and EH-3TVT-ID) based on vinylenebridged oligothiophene applied as donor for the solution-processable bulk-heterojunction organic solar cells (OSCs).Vinylene unit was introduced as π-bridge in th