【摘 要】
：
A new ID zigzag chain coordination polymer, {[Mn(bpp)(bac)2]·(CH3CN)}n1 (bpp =1,3-bis(4-pyridyl)propane, Hbac=benzoylacetone), has been synthesized and charact
【机 构】
：
State Key Laboratory Base of Novel Functional Materials & Preparation Science
论文部分内容阅读
A new ID zigzag chain coordination polymer, {[Mn(bpp)(bac)2]·(CH3CN)}n1 (bpp =1,3-bis(4-pyridyl)propane, Hbac=benzoylacetone), has been synthesized and characterized by FT-IR spectroscopy, thermal analysis and X-ray single-crystal diffraction. In the molecular structure, all Mn atoms locate in an octahedral geometry. The guest CH3CN molecules are included in the 1D channels of the 3D packing structure of 1. Crystal data: C35H35MnN3O4, Mr = 616.60, monoclinic, space group P21/c, a =17.691(4), b = 18.955(4), c = 9.712(6) (A°), β = 93.91(3)°, V = 3249.31(1) (A°)3, Z = 4, Dc=1.260 g/cm3, F(000) = 1292, 2θmax = 54.9°,μ = 0.447 mm-1, the final S = 1.020, R = 0.0693 and wR =0.1497.
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