至今文献报道的纳米金属玻璃体系Fe—C和Fe—M—B(M=Co,Ni等),分别是由Fe(CO)_5在有机溶剂中的热分解和KBH_4在水溶液中还原金属离子的方法制成。由于类金属元素的种类对金属玻璃性质至关重要,我们曾用化学还原法制备Fe-P-B纳米金属玻璃体系,并观察到由于加入磷而出现的电子辐照收缩效应。本文初步考察了反应溶液的初 To date, Fe-C and Fe-M-B (M = Co, Ni, etc.) have been reported in the literature. They are respectively the thermal decomposition of Fe (CO) _5 in organic solvents and the reduction of metal ions in aqueous solution by KBH_4 Method made. Since the kinds of metalloid elements are crucial for the properties of metallic glass, we have prepared the Fe-P-B nano-metallic glass system by chemical reduction and observed the electron irradiation shrinkage effect due to the addition of phosphorus. This paper initially investigated the beginning of the reaction solution