【摘 要】
：
Two homochiral metallosalen complexes,Ni(salen) (salen=(1R,2R)-(-)-diaminocyclohexane-N,N-bis(3-tert-butyl-5-(4-benzoic acid)-salicylidene) 1 and Cu(salen) 2,ha
【机 构】
：
College of Chemistry and Materials Science,School of Chemistry and Chemical Technology,State Key Lab
论文部分内容阅读
Two homochiral metallosalen complexes,Ni(salen) (salen=(1R,2R)-(-)-diaminocyclohexane-N,N-bis(3-tert-butyl-5-(4-benzoic acid)-salicylidene) 1 and Cu(salen) 2,have been synthesized and characterized by IR,microanalysis,TGA,powder and single-crystal X-ray crystallography. Both 1 and 2 crystallize in orthorhombic space group P2_12_12 with Z=4. For 1,α= 12.082(2),b = 15.447(3),c = 18.784(4)(A),V= 3505.7(12) (A)~3,M_r = 731.50,D_c = 1.386 g/cm~3,μ= 0.606 mm~(-1),F(000)=1544,the final GOOF=1.043,R=0.0496 and wR=0.1248 for 4791 observed reflections with Ⅰ> 2σ(Ⅰ). For 2,α=12.181(2),b=15.501(3),c=18.877(4)(A),V= 3564.3(12)(A)~3,M_r=736.33,Dc = 1.372 g/cm~3,μ=0.665 mm~(-1),F(000)=1548,the final GOOF= 1.062,R=0.0575 and wR=0.1508 for 4562 observed reflections with Ⅰ> 20(Ⅰ). The crystal structures of 1 and 2 are isostructural with very similar supramolecular structures. An infinite two-dimensional network is generated by hydrogen bonding interactions and intermolecular π…π interactions.
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