Separating lights into different paths according to the polarization states while keeping their respective path’s polarizations with high purification is keen for polarization multiplex in optical communications. Metallic nanowire gratings with multi-slits in a period are proposed to achieve polarized beam splitters (PBSs) in reflection and diffraction. The setting of multi-slits largely reduces the reflection of photons with a transverse magnetific field via the plasmonic waveguiding effect, which leads to highly polarized output lights with extinction ratio larger than 20 dB in each channel. The proposed reflection/diffraction PBSs enrich the approaches to control the polarization states with the advantages of wide incident angles and flexible beam splitting angles.