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用外循环玻璃无梯度反应器研究了Fe_(4.9)Zn_(0.9)Mg_(0.1),催化剂上丁二烯深度氧化动力学,试验结果服从反应物强吸附双分子反应L-H机理方程 r_(CO_2)=(kb_Db_(O_2)p_Dp_(o_2))/(b_Dp_D+b_(O_2)p_(O_2))~2并求出相应的动力学参数。
The oxidation kinetics of butadiene at Fe 4.9 Zn 0.9 Mg 0.1 (0.1) was investigated by using an external recycle glass gradientless reactor. The experimental results obeyed the r_ (CO_2) equation of the LH mechanism of the strongly adsorbed bimolecular reaction. = (kb_Db_ (O_2) p_Dp_ (o_2)) / (b_Dp_D + b_ (O_2) p_ (O_2)) ~ 2 and find the corresponding kinetic parameters.