Binary solvent (CS2-NMP) has extreme high extraction ability to coals, and it can extract most bitumens out of coals and vitrinites. And large amount of messages on side chains and their distri- bution character in vitrinites should be acquired through flash pyrolysis before and after binary solvent (CS2-NMP) extraction. A few low maturated coals have been selected and vitrinites are handpicked from coals. Then vitrinites have been extracted using different solvents in the order of polarity. Flash pyro- lysis-Gas Chromatography/Mass spectrum has been applied to samples. The result shows that CS2-NMP is efficient for the extraction of vitirnites, giving much higher extraction yield than common solvents. Pro- duction ratio of liquid hydrocarbons in pyrolysates of vitrinites extracted with CS2-NMP is lower than that of raw vitrinites. And relative ratio of each component in pyrolysates has changed apparently. Production ratio of aliphatic hydrocarbons, especially those long chain aliphatics have decreased much after mixed solvent extraction. It shows that bitumens extracted with CS2-NMP have largely contributed to pyrolysates, especially those aliphatics in pyrolysates. Binary solvent (CS2-NMP) has extreme high extraction ability to coals, and it can extract most bitumens out of coals and vitrinites. And large amount of messages on side chains and their distri- bution character in vitrinites should be acquired through flash pyrolysis before and after binary solvent (CS2-NMP) extraction. A few low maturated coals have been selected and vitrinites are handpicked from coals. Then vitrinites have been extracted using different solvents in the order of polarity. Flash pyro-lysis-Gas Chromatography / Mass spectrum has been applied to samples. The result shows that CS2-NMP is efficient for the extraction of vitirnites, giving much higher extraction yield than common solvents. Pro- duction ratio of liquid hydrocarbons in pyrolysates of vitrinites extracted with CS2- of raw vitrinites. And relative ratio of each component in pyrolysates has changed apparently. Production ratio of aliphatic hydrocarbons, especially those long chain aliphati cs have decreased much after mixed solvent extraction. It shows that bitumens extracted with CS2-NMP have greatly contributed to pyrolysates, especially those aliphatics in pyrolysates.