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报道了２个取代三联吡啶配体（４′－苯基－２，２′∶６′，２″－三联吡啶（Ｌ１）和４′－二茂铁基－２，２′∶６′，２″－三联吡啶（Ｌ２））的Ｃｏ（Ⅱ）配合物（［Ｃｏ（Ⅱ）（Ｌ１）２］（ＣｌＯ４）２·４ＣＨ３ＣＮ（１）和［Ｃｏ（Ⅱ）（Ｌ２）２］（ＣｌＯ４）２Ｈ２Ｏ（２））的合成及配体Ｌ２和配合物１和配合物２的晶体结构．电化学研究表明：在配合物２中，由于Ｃｏ２＋的作用，二茂铁基的氧化电位较配体Ｌ２中的二茂铁基的氧化电位有０．１４Ｖ的正移动．同时发现，在配合物１中，Ｃｏ２＋的氧化还原电位较２中Ｃｏ２＋的氧化还原电位有０．０６Ｖ的正移动．说明在配合物２的二茂铁中的Ｆｅ（Ⅱ）与Ｃｏ（Ⅱ）之间存在着由分子片断传递的电子相互作用．
Two substituted terpyridine ligands (4’-phenyl-2,2 ’: 6’, 2 "-terpyridine (L1) and 4’-ferrocene-2,2’6 ’ Co (II) (L1) 2] (ClO4) 2.4CH3CN (1) and [Co (II) (L2) 2] (ClO4) 2H2O (2)) and the crystal structures of ligand L2 and complexes 1 and 2. Electrochemical studies showed that in complex 2, due to the action of Co2 +, the oxidation potential of ferrocenyl groups was 0.14V more positive than the oxidation potential of ferrocenyl groups in ligand L2. It is also found that in complex 1, the redox potential of Co2 + has a positive shift of 0.06V from the redox potential of Co2 + in two phases. It shows that there exists an electronic interaction between Fe (Ⅱ) and Co (Ⅱ) in the ferrocene of the complex 2 through the molecular fragment.