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5. A New Synthetic Route to 12-Oxo-1, 15-pentadecanlactam

A New Synthetic Route to 12-Oxo-1, 15-pentadecanlactam

来源 :中国化学快报（英文版） | 被引量 : 0次 | 上传用户：jj80022084

【摘 要】

：

12-Oxo-1, 15-pentadecanlactam 7 was synthesized from cyclododecanone with a total yield of 36% in a seven-step reaction. The azide 5 to 12-nitro-1, 15-pentadeca

【作 者】

：

Jia Xing HUANG Xiao Mei LIANG 

【机 构】

：

Key Laboratory of Pesticide Chemistry and Application Technology

【出 处】

：

中国化学快报（英文版）

【发表日期】

：

2004年期

【关键词】

：

Macrolactam synthesis ring enlargement 

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论文部分内容阅读

12-Oxo-1, 15-pentadecanlactam 7 was synthesized from cyclododecanone with a total yield of 36% in a seven-step reaction. The azide 5 to 12-nitro-1, 15-pentadecanlactam 6 is the key step featured by direct ring expansion.

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