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合成了两种氮杂大环八聚多酸超分子配合物［Na（N-Ph）aza-15C5（Et2O）］2Na2MO8O26（Ⅰ）和［Na（N－Ph）aza－15C5（Et2O）］2Na2Wo25Mo7.75O26（Ⅱ），用元素分析、IR、1HNMR和H，H－COSY谱进行了表征，并用X射线测定了配合物（Ⅱ）的晶体结构．配合物（Ⅱ）属单斜晶系，空间群为P21/c，晶胞参数为：a=1.7644（4）nm，b=1．3702（3）nm，c=1．4507（3）nm，β=114．02（3）°，Z=2．该类晶体由大环金属销配位阳离子和二维阴离子网络［Na2WxMo8-xO26」2-组成，阴、阳离子分层堆积．研究了苯基氮杂-15-冠-5和与之键合的多酸阴离子的结构及相互关系．发现在苯基氮杂-15-冠-5分别与八错多酸和六聚钨错杂多酸反应所得的产物中，多酸阴离子的聚合度均为8．表明大环化合物的结构与阴离子的结构有一定的对应关系．
Two kinds of aza macrocyclic ocopolymerpolyacid supramolecular complexes [Na (N-Ph) aza-15C5 (Et2O)] 2Na2MO8O26 (Ⅰ) and [Na (N-Ph) aza-15C5 (Et2O)] 2Na2Wo25Mo7 .75O26 (Ⅱ) was characterized by elemental analysis, IR, 1HNMR and H, H-COZY spectra. The crystal structure of complex (Ⅱ) was determined by X-ray diffraction. The complex (Ⅱ) belongs to the monoclinic system with space group P21 / c. The unit cell parameters are a = 1.7644 (4) nm, b = 1.3702 (3) nm and c = 1.4507 , Β = 114.02 (3) °, Z = 2. This type of crystal from macrocyclic metal pin coordination cation and two-dimensional anion network [Na2WxMo8-xO26 "2-, anion, cation layered. The structure and interrelationship between phenylazepin-15-crown-5 and the polyacid anions bonded to them were studied. It was found that the degree of polymerization of the polyanionic anions was 8 in the product of the reaction of phenylazepin-15-crown-5 with octadalanto-polyacid and hexastetra-tungsten heteropolyacid respectively. It shows that the structure of the macrocyclic compound has a certain correspondence with the structure of the anion.