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研究了常压下,温度为450~650℃,停留时间为15.44~4.03s条件下的JP-10(挂式-四氢双环戊二烯)热裂解产物分布.在相对较长的停留时间下,JP-10热裂解转化率对温度很敏感.热裂解主要产物为甲烷、乙烯、丙烯、丁烯、丁二烯、环戊二烯、苯、甲苯、苯乙烯、环戊烯的乙烯基取代物及C5,C6异构体(戊二烯、环戊烯的甲基取代物、环己烯、己二烯和环戊二烯甲基取代物),其中,C1~C4、环戊二烯、苯、甲苯、乙烯基取代环戊烯为初始产物.
The pyrolysis product profiles of JP-10 (pendant-tetrahydro-dicyclopentadiene) under atmospheric pressure at a temperature of 450-650 ° C. for a residence time of 15.44-4.03 s were studied. At relatively long residence times , Pyrolysis rate of JP-10 is sensitive to temperature.The main products of pyrolysis are vinyl substitution of methane, ethylene, propylene, butylene, butadiene, cyclopentadiene, benzene, toluene, styrene and cyclopentene And C5, C6 isomers (pentadiene, methyl substitutes of cyclopentene, cyclohexene, hexadiene and cyclopentadienyl methyl substitutes) in which C1 to C4, cyclopentadiene , Benzene, toluene, vinyl-substituted cyclopentene as the initial product.