一、前言有机锡高分子是一种具有广泛应用前景的新型高分子材料。早期的研究是试图合成象硅橡胶那样的有机聚锡氧烷,但由于合成上的困难而受到了挫折,后来转为合成含有侧基有机锡的高分子,逐渐开发出具有生物活性的高分子材料,获得工业界的重视,并使有机锡高分子化学研究得到新的推动。已开发了几种有机锡的烯类单体的合成路线,各种结构的有机锡聚合物和共聚物的聚合实施方法,以及应用的配方等,几个主要品种已具有工业规模的生产。国际上六十年代有机锡作为防污漆已进入商品化了,这是因为有机锡化合物对藤壶、盘管虫、苔藓虫、海藻等海洋动植物有良好的毒 I. Introduction Organotin polymer is a new type of polymer material with broad application prospects. Earlier research attempted to synthesize organopolysiloxanes, such as silicone rubbers, but suffered setbacks due to synthetic difficulties and later turned to synthesize polymers containing pendant organotin and gradually developed bioactive polymers Materials, get the attention of the industry, and organotin polymer chemistry has been a new push. Several major varieties have been developed on an industrial scale, including the synthesis of several organotin-based ethylenic monomers, methods for the polymerization of various structures of organotin polymers and copolymers, and the formulation used. International tin in the 1960s as antifouling paint has been commercialized, because organotin compounds on barnacles, coil worms, bryozoans, seaweed and other marine animals and plants have a good poison