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采用等量浸渍法制备了一系列Cr-M/ZrO2双金属及单金属氧化物催化剂。CO氧化活性的测定结果表明,贵金属Pd和Pt与Cr之间具有明显的协同催化作用。在Cr-Pd/ZrO2和Cr-Pt/ZrO2上,CO100%转化的温度较在Cr/ZrO2上分别下降了约220℃和130℃。XRD和TPR结果表明,Cr/ZrO2中Cr以表相和体相的Cr2O3存在,体相的Cr2O3与载体ZrO2间发生了强相互作用,从而抑制了ZrO2晶粒间的烧结和t-ZrO2→m-ZrO2的相变,微量Pt或Pd的加入使催化剂的还原性能发生明显变化,催化剂的还原性增强。对微量Pt和Pd在Cr/ZrO2中的作用做了一些探讨
A series of Cr-M / ZrO2 bimetallic and monometallic oxide catalysts were prepared by the same impregnation method. The results of the measurement of CO oxidation activity show that there is a remarkable synergistic catalysis between the noble metals Pd and Pt. On Cr-Pd / ZrO2 and Cr-Pt / ZrO2, the CO 100% conversion temperature was reduced by about 220 ° C and 130 ° C, respectively, over Cr / ZrO2. The results of XRD and TPR show that the Cr in Cr / ZrO2 exists in the form of Cr2O3 in the form of phase and bulk and the strong interaction between Cr2O3 in the bulk and ZrO2 in the bulk and the sintering of ZrO2 grains and the reduction of t-ZrO2 → m -ZrO2 phase transformation, the addition of trace Pt or Pd significantly changes the reduction performance of the catalyst, reducing the catalyst enhanced. The effect of trace Pt and Pd in Cr / ZrO2 is discussed