【摘 要】
：
An unusual inorganic-organic hybrid hexatungstate complex [Cu(phen)3][W6O19] 1(C36H24 CuN6O19W6, Mr= 2011.20) was hydrothermally synthesized and characterized b
【机 构】
：
Institute of Polyoxometalate Chemistry
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An unusual inorganic-organic hybrid hexatungstate complex [Cu(phen)3][W6O19] 1(C36H24 CuN6O19W6, Mr= 2011.20) was hydrothermally synthesized and characterized by singlecrystal X-ray diffraction, IR spectrum, UV-VIS spectrum and elemental analyses. This compound crystallizes in the monoclinic system, space group C2/c with a = 19.1005(11), b = 11.2585(11), c =20.2867(15) (A),β= 102.177(2)°, V= 4264.4 (A)3, μ(MoKa) = 16.691 mm-1, Dc = 3.133 g/cm3, Z= 4,F(000) = 3628, the final R = 0.0338 and wR = 0.0798 for 4090 observed reflections with 1 ＞ 2σ(Ⅰ).The result of structure determination shows that the crystal structure is constructed from [W6O19]2-cluster anions and [Cu(phen)3]2+ complex fragments, which are held together into a three-dimensional network through hydrogen-bonding interactions.
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