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The title compound,[Ag4(L)4](PMBS)4·2H2O (1),where L=2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene,PMBS =p-methylbenzenesulfonate was synthesized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of triclinic,space group P1 with a=0.820 3(2) nm,b=1.322 7(3) nm,c=2.061 0(3) nm,α=76.155(2)°,β=78.651(4)°,γ=89.993(3)°,V=2.126 2(8) nm3,Z=2,Dc=1.644 g·cm-3,F(000)=1 068,R=0.052 4,wR=0.113 6. The Ag atoms are linear coordinated by two N atoms of two L ligands,while the p-methylben-zenesulfonate molecules are included in the lattice and connected to [Ag(L)]n by hydrogen bonding interactions to form a three-dimensional supramolecular structure.
The title compound, [Ag4 (L) 4] (PMBS) 4.2H2O (1) where L = 2,5-bis -methylbenzenesulfonate was synthesized and its crystal structure was determined by X-ray diffraction structure analysis. The crystal is of triclinic, space group P1 with a = 0.820 3 (2) nm, b = 1.322 7 (3) nm, α = 76.155 (2) °, β = 78.651 (4) °, γ = 89.993 (3) °, V = 2.126 2 (8) nm3, Z = 2 and Dc = 1.644 g · cm-3 , F (000) = 1 068, R = 0.052 4, wR = 0.113 6. The Ag atoms are linear coordinated by two N atoms of two L ligands, while the p-methylben- zenesulfonate molecules are included in the lattice and connected to [Ag (L)] n by hydrogen bonding interactions to form a three-dimensional supramolecular structure.