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<正>Two new Co(Ⅱ)coordination polymers {[Co(Htbip)_2(H_2O)_4]·(H_2O)}_n 1 and {[Co_2(tbip)_2(bpa)_(1.5)](H_2tbip)}_n 2(H_2tbip=5-tert-butyl isophthalic acid,bpa=1,2-dis(4-pyridyl) ethane)have been synthesized under hydrothermal conditions and ch