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N-(m-ferrocenylphenyl)-formamide has been synthesized by the reaction of m-ferrocenyl-aniline with DMF, and characterized by elements analysis, IR, 1H NMR, and X-ray structure determination. The crystallized was in the monoclinic, P21/c space group, with a=0.140 94(3) nm, b=0.102 87(2) nm, c=0.100 26(2) nm, β=104.85(3)° and final R indices [I>2σ(I)] R1=0.072 7, wR2=0.184 5. An infinite one-dimensional chain is formed by intermolecular hydrogen bonding N-H...O. Cyclic voltammetry was studied comparing with the parent compound (m-ferrocenylaniline). CCDC: 243511.
N- (m-ferrocenylphenyl) -formamide has been synthesized by the reaction of m-ferrocenyl-aniline with DMF, and characterized by element analysis, IR, 1H NMR, and X-ray structure determination. The crystallized was in monoclinic, P21 / c space group, with a = 0.140 94 (3) nm, b = 0.102 87 (2) nm, c = 0.100 26 (2) nm, β = 104.85 (3) ° and final R indices [I> 2σ )] R1 = 0.072 7, wR2 = 0.184 5. An infinite one-dimensional chain is formed by intermolecular hydrogen bonding NH ... O. Cyclic voltammetry was studied comparing with the parent compound (m-ferrocenylaniline). CCDC: 243511.