【摘 要】
：
Dimethoxyphenol was a widely used substrate in determination of laccases activity.It was surprised,however,that the products of it had not been completely deter
【机 构】
：
Department of Industrial Chemistry Meiji University,Higashi-mita,Tama-ku,Kawasaki 214,Japan,
【出 处】
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Chinese Chemical Letters
论文部分内容阅读
Dimethoxyphenol was a widely used substrate in determination of laccases activity.It was surprised,however,that the products of it had not been completely determined until now.Studies were thus conducted on Rhus laccase (RL) and immobilized Rhus laccase (IRL)-catalyzed oxidation of 2,6-dimethoxyphenol (DMP) in water-organic solvent systems.Only one product,3,3′,5,5′- tetramethoxy-1,1′-biphenyl-4,4′-diol (TMBP),was produced by RL catalysis,and it was thoroughly characterized by FT-IR,NMR and GC-MS,etc.
Dimethoxyphenol was a widely used substrate in determination of laccase activity. It was surprised, however, that the products of it had not been found until now. Studies were thus conducted on Rhus laccase (RL) and immobilized Rhus laccase (IRL) -catalyzed Oxidation of 2,6-dimethoxyphenol (DMP) in water-organic solvent systems. One member product 3,3 ’, 5,5’-tetramethoxy-1,1’- biphenyl-4,4’-diol (TMBP) was produced by RL catalysis, and it was thoroughly characterized by FT-IR, NMR and GC-MS, etc.
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