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研究了在甲醇—吡啶体系中,一系列金属酞菁配合物在光激发下产生单线态氧的能力.结果表明,它们产生1O2能力的顺序如下:ZnPc>AlPcCl≥CrPc>TNCoPc>TNNiPc>MnPc>CoPc>NiPc>Mn(OH)Pc>FeClPc>FePc.并着重讨论了中心金属离子、环取代基对MPc产生1O2能力的影响
The ability of a series of metal phthalocyanine complexes to generate singlet oxygen under photoexcitation was studied in a methanol-pyridine system. The results show that the order of their ability to produce 1O2 is as follows: ZnPc> AlPcCl> CrPc> TNCoPc> TNNiPc> MnPc> CoPc> NiPc> Mn (OH) Pc> FeClPc> FePc. The effects of central metal ions and ring substituents on the ability of MPc to produce 1O2 were also discussed