碳/蒙脱土复合载体的制备及其载铂电催化乙醇氧化性能

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为了进一步提高直接乙醇燃料电池催化剂的性能,在800℃下碳化聚吡咯包覆的蒙脱土,制备碳包覆蒙脱土复合载体.通过多醇还原法在其表面沉积铂纳米颗粒,并考察碳包覆蒙脱土复合载体在电催化乙醇氧化反应中的效果.所制备的样品用X射线衍射仪、扫描电镜、透射电镜和X射线光电子能谱分析了物相结构、表面形貌和组成.电化学结果表明,所合成的碳包覆蒙脱土负载铂催化剂比商业碳(Vulcan XC-72)载铂催化剂具有较大的电化学面积和电催化乙醇氧化活性.
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