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应用电位扫描和电位-时间程序技术,研究了四氢呋喃在铂电极上和在HClO_4溶液中电催化氧化时的吸附中间物.结果表明,在铂表面上存在三种独方形成的吸附中间物.论证了这些吸附中间物的可能构型及其形成机理。
The adsorption intermediates of tetrahydrofuran on Pt electrode and electrocatalytic oxidation in HClO_4 solution were investigated by potentiometric and potentiometric-time program techniques. The results show that there are three kinds of adsorptive intermediates formed on the surface of platinum. The possible configuration of these adsorption intermediates and their formation mechanism.