超分子体系中的分子识别研究(ⅩⅦ)——几种有机硒修饰β-环糊精与脂肪醇的包结配位作用

来源 :高等学校化学学报 | 被引量 : 0次 | 上传用户:xiaoshuishe
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
环糊精双核铜配合物以及磷酰基修饰环糊精可通过离子间的静电相互作用扩展对分子的键合能力和分子选择性[1~4].含有芳香基的修饰环糊精可通过主-客体间的几何互补和诱导楔合作用扩展手性对映体识别能力[5].本文用紫外-可见分光光度技术研究了几种有机硒修饰β... Cyclodextrin binuclear copper complexes and phosphoryl modified cyclodextrins can extend the bonding ability and molecular selectivity of the molecules through the electrostatic interaction between the ions [1 ~ 4]. Aromatics-containing modified cyclodextrins can extend the chiral enantiomeric recognition ability through the host-guest geometric complementation and the induced wedge-binding [5]. In this paper, UV-visible spectrophotometry of several organic selenium modified beta ...
其他文献
目的研究电磁脉冲(EMP)对犬淋巴细胞的损伤效应,并探讨其作用机理。方法用酸性磷酸酯酶细胞化学方法检测T、TH和Ts淋巴细胞,用原位末端标记和免疫细胞化学技术分析淋巴细胞凋亡
The equations ofstate of the neutron star matter are calculated in the relativistic mean-field approximation witl different hyperon coupling constants. The prop
The relation between the stability of icosahedral clusters and the range of interaction potential is discussed.We found that the stability of icosahedral cluste
Theoretical analysis of the DNA dynamics reveals that interaction between the single solitons and plane wave implies Smale-horseshoe chaos in the double helices
将三(苯基氨基甲酸)支链淀粉酯涂敷在硅胶上制成了手性固定相.将支链淀粉与过量的苯异氰酸酯在吡啶中反应得到的苯基氨基甲酸酯溶解并涂敷在用3-氨基丙基三乙氧基硅烷处理过
提出种SWEEP曲面用NURBS逼近的方法,对于截面线的定位,提出了一种定位方法,对于逼近误差控制,可转化为对插值曲线的误差估计.本文算法已在具有自主版权的Gems5.O中实现
By taking into account all the irreducible representations and their components in the electron-phonon interaction (EPI) as well as all the levels and the admix
自从1985年Kroto等[1,2]发现富勒烯(球烯)以来,在化学、物理和材料等领域逐渐地形成了富勒烯的研究热潮,现在人们正将较多注意力投向富勒烯的各类衍生物结构与性能之间内在联系规律的研究,以期望
谷胱甘肽过氧化物酶(GPX,Ec 1.11.1.9)属抗氧化应激酶系,它以还原型谷胱甘肽为底物,催化还原氢过氧化物[1].它能消除体内自由基,防止脂质过氧化,对治疗和预防克山病、心血管