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在水热条件下合成了基于四氟对苯二甲酸的2个二维微孔配位聚合物{[Cd2(IP)2(tfBDC)2(H2O)2]·H2O}n(1)和{[Mn2(IP)2(tfBDC)2(H2O)2]·H2O}n(2)(tfBDC=2,3,5,6-四氟对苯二甲酸,IP=1-H-咪唑[4,5-f][1,10]-菲咯啉)。二维层状结构是44-网状结构,三维超分子结构是由氢键连接相邻的二维层状结构而形成的。2个配位聚合物均用元素分析、热重分析(TGA)、粉末衍射(PXRD)、红外光谱(FT-IR)进行了表征,且对配合物1的荧光性质进行了详细的分析。
Two 2-dimensional microporous coordination polymers based on tetrafluoroterephthalic acid {[Cd2 (IP) 2 (tfBDC) 2 (H2O) 2] · H2O} n (1) and { [Mn2 (IP) 2 (tfBDC) 2 (H2O) 2] · H2O} n (2) (tfBDC = 2,3,5,6-tetrafluoroterephthalic acid, IP = 5-f] [1,10] -phenanthroline). The two-dimensional layered structure is a 44-mesh structure, and the three-dimensional supramolecular structure is formed by hydrogen bonding adjacent two-dimensional layered structures. The two coordination polymers were characterized by elemental analysis, thermogravimetric analysis (TGA), powder diffraction (PXRD) and infrared spectroscopy (FT-IR). The fluorescence properties of complex 1 were analyzed in detail.