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在THF体系中,设计并成功地合成了两种具有平面结构的三嗪类衍生物2,4-二(3,5-二甲基吡唑)-6-二乙胺基-1,3,5-三嗪(简写为Bpz*eaT)和2,4,6-三(3,5-二甲基吡唑)-1,3,5-三嗪(简写为Tpz*T)化合物,并以此为配体,在不同的温度下合成了3种新型配合物Co(Bpz*eaT)Cl2(1),[Co(Bpz*T-O)2]·(COO)2·H2O(2),[Co(Mpz*T-O2)2(H2O)2]·3H2O(3).通过元素分析、红外光谱、紫外光谱、X射线粉末以及X射线单晶衍射方法对配合物进行了表征,并分析了其光谱及结构特征.此外,还对三嗪衍生物在高温条件下发生的原位反应进行了讨论.
In the THF system, two triazine derivative 2,4-bis (3,5-dimethylpyrazolyl) -6-diethylamino-1,3-dioxolane with a planar structure were designed and successfully synthesized. Triazine (abbreviated as Bpz * eaT) and 2,4,6-tris (3,5-dimethylpyrazole) -1,3,5-triazine (abbreviated as Tpz * T) The ligands were synthesized at different temperatures. Three novel complexes, Co (Bpz * eaT) Cl2 (1), [Co (Bpz * TO) 2] · (COO) 2 · H2O (Mpz * T-O2) 2 (H2O) 2] · 3H2O (3). The complex was characterized by elemental analysis, IR, UV, X-ray powder and X-ray single crystal diffraction. Spectral and structural features.In addition, the in situ reaction of triazine derivatives under high temperature was also discussed.