Crusher hammers for the mineral processing industry must meet the demands of both high wear resistance at the hammer head and high impact toughness at the hammer handle. The crusher hammers made of Hadfield steel have typically low service life of less than 40 hours. To solve the problem, a kind of bimetal crusher hammers made of high chromium cast iron(HCCI) and low alloy steel(LAS) has been successfully developed by using liquid-liquid composite casting. The microstructure and composite interface bonding was analyzed using optical microscope, SEM, EDX and XRD. Micrographs indicate that the composite interface is metallurgically bonded with a zigzag shape across the boundary and without unbound region or void. After heat treatment, the composite hammers have shown excellent properties. The hardness of HCCI is at least 63 HRC and its αk is greater than 3.5 J·cm-2; the hardness of LAS is greater than 35 HRC and its αk is no less than 80 J·cm-2. Diffusion of elements takes place at the interface and forms a transition region. The micro hardness increases from LAS to the interface and then to HCCI. Wear comparison was made separately between the bimetal composite hammer and a Hadfield steel hammer in two quarries of Jilin province and Liaoning province. The results showed that the liquid-liquid bimetal composite hammers did not have the falling off of hammer head or impact fracture phenomenon, and their service life was 3.75 times as long as that of the Hadfield steel hammers. Crusher hammers for the mineral processing industry must meet the demands of both high wear resistance at the hammer head and high impact toughness at the hammer handle. The crusher hammers made of Hadfield steel have typically low service life of less than 40 hours. To solve the problem, a kind of bimetal crusher hammers made of high chromium cast iron (HCCI) and low alloy steel (LAS) has been successfully developed by using liquid-liquid composite casting. The microstructure and composite interface bonding was analyzed using optical microscope, SEM, EDX and XRD. Micrographs indicate that the composite interface is metallurgically bonded with a zigzag shape across the boundary and without unbound region or void. After heat treatment, the composite hammers have shown excellent properties. The hardness of HCCI is at least 63 HRC and its αk is greater than 3.5 J · cm-2; the hardness of LAS is greater than 35 HRC and its αk is no less than 80 J · cm-2. Diffusion of elements takes place at t The comparison between the bimetal composite hammer and a Hadfield steel hammer in two quarries of Jilin province and Liaoning province. The results showed that the liquid-liquid bimetal composite hammers did not the the off off of hammer head or impact fracture phenomenon, and their service life was 3.75 times as long as that of the Hadfield steel hammers.