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5. From discrete [Mn₄] cluster to 1D complex: Two new mixed-valence manganese co

From discrete [Mn₄] cluster to 1D complex: Two new mixed-valence manganese co

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：dadiguilai

【摘 要】

：

A tetranuclear manganese complex [Mn4(HL)4(MeOH)4(SCN)2]·3MeOH (1) and a one-dimensional assembly of [Mn4] units, [Mn4(HL)4(MeOH)4(N(CN)2)2]·2.5MeOH (

【出 处】

：

中国科学：化学英文版

【发表日期】

：

2009年9期

【关键词】

：

TETRANUCLEAR manganese COMPLEX 1D COMPLEX MAGNETIC properties SLOW MAGNETIC rela 

【基金项目】

：

Supported by the National Natural Science Foundation of China (Grant Nos. 20471032 & 50672037) ,the Natural Science Foundation of Tianjin (Grant No. 09JCYBJC05600)

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A tetranuclear manganese complex [Mn4(HL)4(MeOH)4(SCN)2]·3MeOH (1) and a one-dimensional assembly of [Mn4] units, [Mn4(HL)4(MeOH)4(N(CN)2)2]·2.5MeOH (2) (H3L = 2,6-bis(hydroxymethyl)-4-methyl-phenol), have been synthesized and studied. Complexes

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