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手性配位聚合物因其结构多样性、可调控性以及潜在的多功能性,已经成为当前化学和材料学的研究热点。在合成中,可以通过选择特定的非手性配体、手性配体、手性溶剂或手性模板剂等来构筑手性配位聚合物。此外,还可以选择特定的金属离子赋予目标手性配位聚合物光、电、磁、催化和非线性光学等性能。本文详细综述了近年来纯手性配位聚合物的合成方法,以及在手性分离、手性催化、非线性光学、铁电和多铁等领域的应用研究进展。最后,对手性配位聚合物的合成方法及应用前景进行了展望。
Chiral coordination polymers have become hot topics in chemistry and materials science due to their structural diversity, regulatability and potential versatility. In the synthesis, chiral coordination polymers can be constructed by selecting specific achiral ligands, chiral ligands, chiral solvents, or chiral templating agents. In addition, specific metal ions can be selected to give the target chiral coordination polymers optical, electrical, magnetic, catalytic, and nonlinear optical properties. This review summarizes the synthesis methods of pure chiral coordination polymers in recent years and the progress in the application of chiral separation, chiral catalysis, nonlinear optics, ferroelectric and multiferroic fields. Finally, the synthesis method and application prospect of the ploymers of coordination polymers are prospected.