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The title compound was synthesized and its structure solved. The formula is [Et4N]3[Fe3(SPh)3Br3Cl3]. M=1231.95, monoclinic, space group C2/c, a=24.569(4), b=13.504(2), c=18.348.(3)A, β=110.78(1)°, V=5691(3)A3, Z=4, Dm= 1.41, Dc=1.44-g/cm3. The flat structure of the anion has. a planar [Fe3S3] ring and three phenyl groups. Statistical distribution of chlorine and bromine atoms on two sides of the [Fe3S3] plane results in a C2 symmetry of the anion.
The title compound was synthesized and its structure solved. The formula is [Et4N] 3 [Fe3 (SPh) 3Br3Cl3]. M = 1231.95, monoclinic, space group C2 / c, a = 24.569 (4), b = , c = 18.348 (3) A, β = 110.78 (1) °, V = 5691 (3) A3, Z = 4, Dm = 1.41, Dc = 1.44-g / cm3. a planar [Fe3S3] ring and three phenyl groups. Statistical distribution of chlorine and bromine atoms on two sides of the [Fe3S3] plane results in a C2 symmetry of the anion.